Ontology highlight
ABSTRACT:
SUBMITTER: Pota K
PROVIDER: S-EPMC10019750 | biostudies-literature | 2023 Apr
REPOSITORIES: biostudies-literature
Pota Kristof K Johnston Hannah M HM Madarasi Enikő E Tircsó Gyula G Green Kayla N KN
Journal of inorganic biochemistry 20230109
Rigidification of the ligand scaffolds has been a particular mechanism of interest employed to achieve properties suitable for MRI contrast, catalysis, or other applications of metal complexes. Towards the goal of targeting a 15-anePyN<sub>5</sub>Pip type ligand, a serendipitous isolation of a 30-anePy<sub>2</sub>N<sub>10</sub>Pip<sub>2</sub> aza-macrocycle was achieved, instead. X-ray diffraction and determination of pK<sub>a</sub> events were carried out and compared to 17-anePyN<sub>5</sub>Pi ...[more]