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Crystal structure of trimeth-yl({tris-[(phenyl-sulfan-yl)meth-yl]sil-yl}meth-oxy)silane and Hirshfeld surface analysis of 3-bromo-2,2-bis-(bromo-meth-yl)propan-1-ol.

ABSTRACT: Trimeth-yl({tris-[(phenyl-sulfan-yl)meth-yl]sil-yl}meth-oxy)silane (3), C26H32OS3Si, is a new ligand for transition-metal coordination chemistry derived from 3-bromo-2,2-bis-(bromo-meth-yl)propan-1-ol (1), C5H9Br3O, through silylation and following exchange of bromine groups with NaSPh. Silylated thio-ether ligand 3 crystallizes in the centrosymmetric space group C2/c. Bromo-methyl-alcohol 1 crystallizes in the space group P in the triclinic crystal system with four mol-ecules in the asymmetric unit. Analysis of the Hirshfeld surface shows structure-defining inter-actions for bromo-methyl-alcohol 1, resulting in inter-molecular hydrogen bonds between the hydroxyl groups along the a-axis direction.

SUBMITTER: Wappelhorst JF 

PROVIDER: S-EPMC10088301 | biostudies-literature | 2023 Mar

REPOSITORIES: biostudies-literature

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Crystal structure of trimeth-yl({tris-[(phenyl-sulfan-yl)meth-yl]sil-yl}meth-oxy)silane and Hirshfeld surface analysis of 3-bromo-2,2-bis-(bromo-meth-yl)propan-1-ol.

Wappelhorst Jan Frederick JF   Wattenberg Jonathan J   Strohmann Carsten C  

Acta crystallographica. Section E, Crystallographic communications 20230315 Pt 4

Trimeth-yl({tris-[(phenyl-sulfan-yl)meth-yl]sil-yl}meth-oxy)silane (<b>3</b>), C<sub>26</sub>H<sub>32</sub>OS<sub>3</sub>Si, is a new ligand for transition-metal coordination chemistry derived from 3-bromo-2,2-bis-(bromo-meth-yl)propan-1-ol (<b>1</b>), C<sub>5</sub>H<sub>9</sub>Br<sub>3</sub>O, through silylation and following exchange of bromine groups with NaSPh. Silylated thio-ether ligand <b>3</b> crystallizes in the centrosymmetric space group <i>C</i>2/<i>c</i>. Bromo-methyl-alcohol <b>1</  ...[more]

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