Selective Electrochemical Hydrogenation of Phenol with Earth-abundant Ni-MoO₂ Heterostructured Catalysts: Effect of Oxygen Vacancy on Product Selectivity.

ABSTRACT: Herein, we report highly efficient carbon supported Ni-MoO₂ heterostructured catalysts for the electrochemical hydrogenation (ECH) of phenol in 0.10 M aqueous sulfuric acid (pH 0.7) at 60 °C. Highest yields for cyclohexanol and cyclohexanone of 95 % and 86 % with faradaic efficiencies of ∼50 % are obtained with catalysts bearing high and low densities of oxygen vacancy (O_v ) sites, respectively. In situ diffuse reflectance infrared spectroscopy and density functional theory calculations reveal that the enhanced phenol adsorption strength is responsible for the superior catalytic efficiency. Furthermore, 1-cyclohexene-1-ol is an important intermediate. Its hydrogenation route and hence the final product are affected by the O_v density. This work opens a promising avenue to the rational design of advanced electrocatalysts for the upgrading of phenolic compounds.

SUBMITTER: Zhou P 

PROVIDER: S-EPMC10107486 | biostudies-literature | 2023 Feb

REPOSITORIES: biostudies-literature