Dataset Information

Copper-/Zinc-Doped TiO₂ Nanopowders Synthesized by Microwave-Assisted Sol-Gel Method.

ABSTRACT: Using the microwave-assisted sol-gel method, Zn- and Cu-doped TiO₂ nanoparticles with an anatase crystalline structure were prepared. Titanium (IV) butoxide was used as a TiO₂ precursor, with parental alcohol as a solvent and ammonia water as a catalyst. Based on the TG/DTA results, the powders were thermally treated at 500 °C. XRD and XRF revealed the presence of a single-phase anatase and dopants in the thermally treated nanoparticles. The surface of the nanoparticles and the oxidation states of the elements were studied using XPS, which confirmed the presence of Ti, O, Zn, and Cu. The photocatalytic activity of the doped TiO₂ nanopowders was tested for the degradation of methyl-orange (MO) dye. The results indicate that Cu doping increases the photoactivity of TiO₂ in the visible-light range by narrowing the band-gap energy.

SUBMITTER: Predoana L

PROVIDER: S-EPMC10137937 | biostudies-literature | 2023 Mar

REPOSITORIES: biostudies-literature

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Copper-/Zinc-Doped TiO2 Nanopowders Synthesized by Microwave-Assisted Sol-Gel Method.

Predoană Luminița L Petcu Gabriela G Preda Silviu S Pandele-Cușu Jeanina J Petrescu Simona Viorica SV Băran Adriana A Apostol Nicoleta G NG Costescu Ruxandra M RM Surdu Vasile-Adrian VA Vasile Bogdan Ştefan BŞ Ianculescu Adelina C AC

Gels (Basel, Switzerland) 20230323 4

Using the microwave-assisted sol-gel method, Zn- and Cu-doped TiO2 nanoparticles with an anatase crystalline structure were prepared. Titanium (IV) butoxide was used as a TiO2 precursor, with parental alcohol as a solvent and ammonia water as a catalyst. Based on the TG/DTA results, the powders were thermally treated at 500 °C. XRD and XRF revealed the presence of a single-phase anatase and dopants in the thermally treated nanoparticles. The surface of the nanoparticles and ...[more]

PMID: 37102879

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Project description:Titanium dioxide (TiO2) in the form of thin films has attracted enormous attention for photocatalysis. It combines the fundamental properties of TiO2 as a large bandgap semiconductor with the advantage of thin films, making it competitive with TiO2 powders for recycling and maintenance in photocatalytic applications. There are many aspects affecting the photocatalytic performance of thin film structures, such as the nanocrystalline size, surface morphology, and phase composition. However, the quantification of each influencing aspect needs to be better studied and correlated. Here, we prepared a series of TiO2 thin films using a sol-gel process and spin-coated on p-type, (100)-oriented silicon substrates with a native oxide layer. The as-deposited TiO2 thin films were then annealed at different temperatures from 400 °C to 800 °C for 3 h in an ambient atmosphere. This sample synthesis provided systemic parameter variation regarding the aspects mentioned above. To characterize thin films, several techniques were used. Spectroscopic ellipsometry (SE) was employed for the investigation of the film thickness and the optical properties. The results revealed that an increasing annealing temperature reduced the film thickness with an increase in the refractive index. Atomic force microscopy (AFM) was utilized to examine the surface morphology, revealing an increased surface roughness and grain sizes. X-ray diffractometry (XRD) and UV-Raman spectroscopy were used to study the phase composition and crystallite size. The annealing process initially led to the formation of pure anatase, followed by a transformation from anatase to rutile as the annealing temperature increased. An overall enhancement in crystallinity was also observed. The photocatalytic properties of the thin films were tested using the photocatalytic decomposition of acetone gas in a home-built solid (photocatalyst)-gas (reactant) reactor. The composition of the gas mixture in the reaction chamber was monitored using in situ Fourier transform infrared spectroscopy. Finally, all of the structural and spectroscopic characteristics of the TiO2 thin films were quantified and correlated with their photocatalytic properties using a correlation matrix. This provided a good overview of which film properties affect the photocatalytic efficiency the most.

Dataset Information

Copper-/Zinc-Doped TiO₂ Nanopowders Synthesized by Microwave-Assisted Sol-Gel Method.

Publications

Copper-/Zinc-Doped TiO<sub>2</sub> Nanopowders Synthesized by Microwave-Assisted Sol-Gel Method.

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