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The Photocatalytic Activity of CaTiO₃ Derived from the Microwave-Melting Heating Process of Blast Furnace Slag.

ABSTRACT: The extraction of titanium-bearing components in the form of CaTiO₃ is an efficient utilization of blast furnace slag. The photocatalytic performance of this obtained CaTiO₃ (MM-CaTiO₃) as a catalyst for methylene blue (MB) degradation was evaluated in this study. The analyses indicated that the MM-CaTiO₃ had a completed structure with a special length-diameter ratio. Furthermore, the oxygen vacancy was easier to generate on a MM-CaTiO₃(110) plane during the photocatalytic process, contributing to improving photocatalytic activity. Compared with traditional catalysts, MM-CaTiO₃ has a narrower optical band gap and visible-light responsive performance. The degradation experiments further confirmed that the photocatalytic degradation efficiency of pollutants by using MM-CaTiO₃ was 3.2 times that of pristine CaTiO₃ in optimized conditions. Combined with molecular simulation, the degradation mechanism clarified that acridine of MB molecular was stepwise destroyed by using MM-CaTiO₃ in short times, which is different from demethylation and methylenedioxy ring degradation by using TiO₂. This study provided a promising routine for using solid waste to obtain catalysts with excellent photocatalytic activity and was found to be in keeping with sustainable environmental development.

SUBMITTER: Xie J

PROVIDER: S-EPMC10142369 | biostudies-literature | 2023 Apr

REPOSITORIES: biostudies-literature

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The Photocatalytic Activity of CaTiO3 Derived from the Microwave-Melting Heating Process of Blast Furnace Slag.

Xie Jun J Ye Qing Q Zhou Jianghao J Liao Yue Y Qian Gongming G

Nanomaterials (Basel, Switzerland) 20230419 8

The extraction of titanium-bearing components in the form of CaTiO3 is an efficient utilization of blast furnace slag. The photocatalytic performance of this obtained CaTiO3 (MM-CaTiO3) as a catalyst for methylene blue (MB) degradation was evaluated in this study. The analyses indicated that the MM-CaTiO3 had a completed structure with a special length-diameter ratio. Furthermore, the oxygen vacancy was easier to generate on a MM-CaTiO3(110) ...[more]

PMID: 37110996

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Project description:The decommissioning process of nuclear power facilities renders hundreds of thousands of tons of various types of waste. Of these different waste types, the amount of concrete waste (CW) varies greatly depending on the type of facility, operating history, and regulation standards. From the previous decommissioning projects, CW was estimated to comprise 60-80 wt.% of the total weight of radioactive wastes. This represents a significant technical challenge to any decommissioning project. Furthermore, the disposal costs for the generated concrete wastes are a substantial part of the total budget for any decommissioning project. Thus, the development of technologies effective for the reduction and recycling of CW has become an urgent agenda globally. Blast furnace slag (BFS) is an industrial byproduct containing a sufficient amount (higher than 30%) of CaO and it can be used as a substitute for ordinary Portland cement (OPC). However, there have been few studies on the application of BFS for the treatment of radioactive waste from decommissioning processes. This study was conducted to evaluate the performance of the solidification agent using ground granulated BFS (SABFS) to pack radioactive wastes, such as the coarse aggregates of CW (CACW), waste soil (WS), and metal waste (MW). The analytical results indicated that the CaO content of the ground granulated BFS was 36.8% and it was confirmed that calcium silicate hydrate (CSH) could be activated as the precursor of the hydration reactions. In addition, the optimum water-to-binder ratio was determined to be 0.25 and Ca(OH)2 and CaSO4 were found to be the most effective alkaline and sulfate activators for improving the compressive strength of the SABFS. The maximum packing capacities of the SABFS were determined to be 9 and 13 wt.% for WC and WM, respectively, when the content of CW was fixed at 50 wt.%. The results of the leaching tests using SABFS containing radioactive wastes contaminated with Co, Cs, and Sr indicated that their leachability indices met the acceptance level for disposal. Consequently, the SABFS can be used as a solidifying agent for the safe disposal of radioactive waste.

Dataset Information

The Photocatalytic Activity of CaTiO₃ Derived from the Microwave-Melting Heating Process of Blast Furnace Slag.

Publications

The Photocatalytic Activity of CaTiO<sub>3</sub> Derived from the Microwave-Melting Heating Process of Blast Furnace Slag.

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