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Ordered growth of metal oxides in patterned multi-angle microstructures.


ABSTRACT: Herein, we report a facile method combining top-down patterning transfer and bottom-up nanorod growth for preparing large-area and ordered TiO2 nanorod arrays. Pre-crystallization seeding was patterned with nanostructured morphologies via interfacial tension-driven precursor solution scattering on various types and period templates. This is a widely applicable strategy for capillary force-driven interfacial patterns, which also shows great operability in complex substrate morphologies with multiple-angle mixing. Moreover, the customized patterned lithographic templates containing English words, Arabic numerals, and Chinese characters are used to verify the applicability and controllability of this hybrid method. In general, our work provides a versatile strategy for the low-cost and facile preparation of hydrothermally growable metal oxide (e.g., ZnO and MnO2) nanostructures with potential applications in the fields of microelectronic devices, photoelectric devices, energy storage, and photocatalysis.

SUBMITTER: Ji Z 

PROVIDER: S-EPMC10234148 | biostudies-literature | 2023 May

REPOSITORIES: biostudies-literature

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Ordered growth of metal oxides in patterned multi-angle microstructures.

Ji Zhenkai Z   Sun Min M   Chen Tiantian T   Shen Xinyi X   Xu Xiuzhen X   Zhong Yan Y   Wang Dadong D   Ma Jiwei J   Chen Bo B   Yi Zhiguo Z   Xu Xiaobin X  

RSC advances 20230501 24


Herein, we report a facile method combining top-down patterning transfer and bottom-up nanorod growth for preparing large-area and ordered TiO<sub>2</sub> nanorod arrays. Pre-crystallization seeding was patterned with nanostructured morphologies <i>via</i> interfacial tension-driven precursor solution scattering on various types and period templates. This is a widely applicable strategy for capillary force-driven interfacial patterns, which also shows great operability in complex substrate morph  ...[more]

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