Dataset Information

Zirconium Component Modified Porous Nanowood for Efficient Removal of Phosphate from Aqueous Solutions.

ABSTRACT: Rapid urban industrialization and agricultural production have led to the discharge of excessive phosphate into aquatic systems, resulting in a rise in water pollution. Therefore, there is an urgent need to explore efficient phosphate removal technologies. Herein, a novel phosphate capture nanocomposite (PEI-PW@Zr) with mild preparation conditions, environmental friendliness, recyclability, and high efficiency has been developed by modifying aminated nanowood with a zirconium (Zr) component. The Zr component imparts the ability to capture phosphate to the PEI-PW@Zr, while the porous structure provides a mass transfer channel, resulting in excellent adsorption efficiency. Additionally, the nanocomposite maintains more than 80% phosphate adsorption efficiency even after ten adsorption-desorption cycles, indicating its recyclability and potential for repeated use. This compressible nanocomposite provides novel insights into the design of efficient phosphate removal cleaners and offers potential approaches for the functionalization of biomass-based composites.

SUBMITTER: Chu Z

PROVIDER: S-EPMC10254632 | biostudies-literature | 2023 Jun

REPOSITORIES: biostudies-literature

ACCESS DATA

Publications

Zirconium Component Modified Porous Nanowood for Efficient Removal of Phosphate from Aqueous Solutions.

Chu Zhuangzhuang Z Wang Wei W Yin Mengping M Yang Zhuohong Z

Nanomaterials (Basel, Switzerland) 20230605 11

Rapid urban industrialization and agricultural production have led to the discharge of excessive phosphate into aquatic systems, resulting in a rise in water pollution. Therefore, there is an urgent need to explore efficient phosphate removal technologies. Herein, a novel phosphate capture nanocomposite (PEI-PW@Zr) with mild preparation conditions, environmental friendliness, recyclability, and high efficiency has been developed by modifying aminated nanowood with a zirconium (Zr) component. The ...[more]

PMID: 37299711

Similar Datasets

Project description:The treatment of wastewater containing heavy metals and the utilization of wool waste are very important for the sustainable development of textile mills. In this study, the wool keratin modified magnetite (Fe3O4) powders were fabricated by using wool waste via a co-precipitation technique for removal of Cu2+ ions from aqueous solutions. The morphology, chemical compositions, crystal structure, microstructure, magnetism properties, organic content, and specific surface area of as-fabricated powders were systematically characterized by various techniques including field emission scanning electron microscopy (FESEM), energy dispersive spectroscopy (EDS), X-ray diffraction (XRD), transmission electron microscopy (TEM), X-ray photoelectron spectroscopy (XPS), vibrating sample magnetometer (VSM), thermogravimetric (TG) analysis, and Brunauer-Emmett-Teller (BET) surface area analyzer. The effects of experimental parameters such as the volume of wool keratin hydrolysate, the dosage of powder, the initial Cu2+ ion concentration, and the pH value of solution on the adsorption capacity of Cu2+ ions by the powders were examined. The experimental results indicated that the Cu2+ ion adsorption performance of the wool keratin modified Fe3O4 powders exhibited much better than that of the chitosan modified ones with a maximum Cu2+ adsorption capacity of 27.4 mg/g under favorable conditions (0.05 g powders; 50 mL of 40 mg/L CuSO4; pH 5; temperature 293 K). The high adsorption capacity towards Cu2+ ions on the wool keratin modified Fe3O4 powders was primarily because of the strong surface complexation of -COOH and -NH2 functional groups of wool keratins with Cu2+ ions. The Cu2+ ion adsorption process on the wool keratin modified Fe3O4 powders followed the Temkin adsorption isotherm model and the intraparticle diffusion and pseudo-second-order adsorption kinetic models. After Cu2+ ion removal, the wool keratin modified Fe3O4 powders were easily separated using a magnet from aqueous solution and efficiently regenerated using 0.5 M ethylene diamine tetraacetic acid (EDTA)-H2SO4 eluting. The wool keratin modified Fe3O4 powders possessed good regenerative performance after five cycles. This study provided a feasible way to utilize waste wool textiles for preparing magnetic biomass-based adsorbents for the removal of heavy metal ions from aqueous solutions.

Dataset Information

Zirconium Component Modified Porous Nanowood for Efficient Removal of Phosphate from Aqueous Solutions.

Publications

Zirconium Component Modified Porous Nanowood for Efficient Removal of Phosphate from Aqueous Solutions.

Similar Datasets

OmicsDI is part of the ELIXIR infrastructure

Tweets