CO₂-laser-induced carbonization of calcium chloride-treated chitin nanopaper for applications in solar thermal heating.

ABSTRACT: Remarkable progress has been made in the development of carbonized chitin nanofiber materials for various functional applications, including solar thermal heating, owing to their N- and O-doped carbon structures and sustainable nature. Carbonization is a fascinating process for the functionalization of chitin nanofiber materials. However, conventional carbonization techniques require harmful reagents, high-temperature treatment, and time-consuming processes. Although CO₂ laser irradiation has progressed as a facile and second-scale high-speed carbonization process, CO₂-laser-carbonized chitin nanofiber materials and their applications have not yet been explored. Herein, we demonstrate the CO₂-laser-induced carbonization of chitin nanofiber paper (denoted as chitin nanopaper) and investigate the solar thermal heating performance of the CO₂-laser-carbonized chitin nanopaper. While the original chitin nanopaper was inevitably burned out by CO₂ laser irradiation, CO₂-laser-induced carbonization of the chitin nanopaper was achieved by pretreatment with calcium chloride as a combustion inhibitor. The CO₂-laser-carbonized chitin nanopaper exhibits excellent solar thermal heating performance; its equilibrium surface temperature under 1 sun irradiation is 77.7 °C, which is higher than those of the commercial nanocarbon films and the conventionally carbonized bionanofiber papers. This study paves the way for the high-speed fabrication of carbonized chitin nanofiber materials and their application in solar thermal heating toward the effective utilization of solar energy as heat.

SUBMITTER: Yeamsuksawat T 

PROVIDER: S-EPMC10258603 | biostudies-literature | 2023 Jun

REPOSITORIES: biostudies-literature