Single-particle dispersion of carbon dots in the nano-hydroxyapatite lattice achieving solid-state green fluorescence.

ABSTRACT: Carbon dots (CDs), as new carbon nanomaterials, have potential applications in multiple fields due to their superior optical properties, good biocompatibility, and easy preparation. However, CDs are typically an aggregation-caused quenching (ACQ) material, which has a huge limitation on the practical application of CDs. To solve this problem, in this paper, CDs were prepared by the solvothermal method using citric acid and o-phenylenediamine as precursors and dimethylformamide as solvent. Then using CDs as nucleating agents, solid-state green fluorescent CDs were synthesized by in situ growth of nano-hydroxyapatite (HA) crystals on the surface of CDs. The results show that CDs are stably dispersed single-particlely in the form of bulk defects in the nano-HA lattice matrices with a dispersion concentration of 3.10%, and solid-state green fluorescence of CDs is achieved with a stable emission wavelength peak position near 503 nm, which provides a new solution to the ACQ problem. CDs-HA nanopowders were further used as LED phosphors to obtain bright green LEDs. In addition, CDs-HA nanopowders showed excellent performance in cell imaging (mBMSCs and 143B) applications, which provides a new scheme for further applications of CDs in the field of cell imaging and even in vivo imaging.

SUBMITTER: Wang L 

PROVIDER: S-EPMC10263101 | biostudies-literature | 2023 Jun

REPOSITORIES: biostudies-literature