Carbonaceous Material Modified MoO₂ Nanospheres with Oxygen Vacancies for Enhanced Visible-Light Photocatalytic Oxidative Coupling of Benzylamine.

ABSTRACT: Surface oxygen vacancy (OV) plays a pivotal role in the activation of molecular oxygen and separation of electrons and holes in photocatalysis. Herein, carbonaceous materials-modified MoO₂ nanospheres with abundant surface OVs (MoO₂/C-OV) were successfully synthesized via glucose hydrothermal processes. In situ introduction of carbonaceous materials triggered a reconstruction of the MoO₂ surface, which introduced abundant surface OVs on the MoO₂/C composites. The surface oxygen vacancies on the obtained MoO₂/C-OV were confirmed via electron spin resonance spectroscopy (ESR) and X-ray photoelectron spectroscopy (XPS). The surface OVs and carbonaceous materials boosted the activation of molecular oxygen to singlet oxygen (¹O₂) and superoxide anion radical (•O₂^-) in selectively photocatalytic oxidation of benzylamine to imine. The conversion of benzylamine was 10 times that of pristine MoO₂ nanospheres with a high selectivity under visible light irradiation at 1 atm air pressure. These results open an avenue to modify Mo-based materials for visible light-driven photocatalysis.

SUBMITTER: Chang Y 

PROVIDER: S-EPMC10302678 | biostudies-literature | 2023 Jun

REPOSITORIES: biostudies-literature