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Magnetic Polymer Actuators with Self-Sensing Resistive Bending Response Based on Ternary Polymer Composites.

ABSTRACT: A multifunctional polymer-based composite has been designed based on poly(vinylidene fluoride) (PVDF) as polymer matrix and cobalt ferrite (CoFe₂O₄, CFO) and multiwalled carbon nanotubes (MWCNTs) as fillers, allowing to combine magnetic and electrical responses. The composites were prepared by solvent casting with a fixed 20 wt % concentration of CFO and varying the MWCNTs content between 0 and 3 wt %, allowing to tailor the electrical behavior. The morphology, polymer phase, and thermal and magnetic properties are nearly independent of the MWCNT filler content within the polymer matrix. On the other hand, the mechanical and electrical properties strongly depend on the MWCNT content and a maximum d.c. electrical conductivity value of 4 × 10^-4 S·cm^-1 has been obtained for the 20 wt %CFO-3 wt %MWCNT/PVDF sample, which is accompanied by an 11.1 emu·g^-1 magnetization. The suitability of this composite for magnetic actuators with self-sensing strain characteristics is demonstrated with excellent response and reproducibility.

SUBMITTER: Garcia Diez A

PROVIDER: S-EPMC10308843 | biostudies-literature | 2023 Jun

REPOSITORIES: biostudies-literature

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Magnetic Polymer Actuators with Self-Sensing Resistive Bending Response Based on Ternary Polymer Composites.

García Díez Ander A Pereira Nelson N Tubio Carmen R CR Vilas-Vilela Jose Luis JL Costa Carlos M CM Lanceros-Mendez Senentxu S

ACS applied electronic materials 20230530 6

A multifunctional polymer-based composite has been designed based on poly(vinylidene fluoride) (PVDF) as polymer matrix and cobalt ferrite (CoFe<sub>2</sub>O<sub>4</sub>, CFO) and multiwalled carbon nanotubes (MWCNTs) as fillers, allowing to combine magnetic and electrical responses. The composites were prepared by solvent casting with a fixed 20 wt % concentration of CFO and varying the MWCNTs content between 0 and 3 wt %, allowing to tailor the electrical behavior. The morphology, polymer phas ...[more]

PMID: 37396056

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Project description:This work aimed to monitor, through the changes in electrical resistance, the evolution of the mechanical properties due to aging caused by water sorption in carbon nanotube-based epoxy composites. The epoxy/CNT nanocomposites were prepared by dispersing the filler in the precursor through the ultra-sonication process and mixing the hardener by mechanical stirring. After an evaluation of the electrical properties, detected through a two-probe electrical measurement method, of nanocomposites at different percentages by weight of the filler (0.025, 0.05, 0.1, 0.3, 0.5, and 1.0), a concentration (0.1% by weight), close to that of the electrical percolation threshold, was chosen to evaluate the resistive response. This specific concentration was selected in order to obtain maximized values of the variation detected for the changes in the electrical resistance resulting from phenomena of structural relaxations/rearrangements due to water absorption. In particular, the electrical conductivity value switched from 8.2 × 10-14 S/m for the unfilled epoxy resin to 6.3 × 10-2 S/m for carbon nanotube-based epoxy composite at 0.1% by weight of the nanofiller. The water sorption caused a reduction in the mechanical properties (storage modulus and tan δ) due to swelling and plasticization phenomena, which caused the structural reorganization of the conductive interparticle contacts in the matrix with a consequent variation in the electrical resistance of the material. The found 'non-Fickian' water diffusion behavior was very similar to the variation in the electrical resistance with time. This last correlation allows the association of the measurement of the electrical resistance with the quantity of absorbed water and, therefore, with the aging of the material to water absorption, through the sensitivity factor (β). The resistive nature of the composite can be used to monitor the amount of water absorption and the changes in the structure of the material subject to water aging.

Dataset Information

Magnetic Polymer Actuators with Self-Sensing Resistive Bending Response Based on Ternary Polymer Composites.

Publications

Magnetic Polymer Actuators with Self-Sensing Resistive Bending Response Based on Ternary Polymer Composites.

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