Dataset Information

Quantifying Ligand Binding to the Surface of Metal-Organic Frameworks.

ABSTRACT: The binding of molecules to the exterior surface of metal-organic frameworks (MOFs) is not a well-understood phenomenon. Herein, the surface chemistry of three MOFs, UiO-66, MIL-88B-NH₂, and ZIF-8, is investigated using dye-displacement experiments. MOF particle surfaces were modified with ligand-appended BODIPY dyes. The ability of the coordinated dyes to be displaced by a variety of exogenous ligands was measured by ultraviolet-visible spectroscopy. This method allowed for measurement of apparent binding constants for different ligands to the MOF surface. As might be expected, ligand affinity was dependent on the nature of the underlying metal-ligand composition of the MOF. This work provides a quantitative evaluation of ligand binding to MOF surfaces and important insights for the modulation, modification, and manipulation of MOFs.

SUBMITTER: Wang A

PROVIDER: S-EPMC10401703 | biostudies-literature | 2023 Aug

REPOSITORIES: biostudies-literature

ACCESS DATA

Publications

Quantifying Ligand Binding to the Surface of Metal-Organic Frameworks.

Wang Austin A Barcus Kyle K Cohen Seth M SM

Journal of the American Chemical Society 20230724 30

The binding of molecules to the exterior surface of metal-organic frameworks (MOFs) is not a well-understood phenomenon. Herein, the surface chemistry of three MOFs, UiO-66, MIL-88B-NH<sub>2</sub>, and ZIF-8, is investigated using dye-displacement experiments. MOF particle surfaces were modified with ligand-appended BODIPY dyes. The ability of the coordinated dyes to be displaced by a variety of exogenous ligands was measured by ultraviolet-visible spectroscopy. This method allowed for measureme ...[more]

PMID: 37487227

Similar Datasets

Project description:Metal-organic frameworks (MOFs), as a new type of nanomaterial, have been rapidly developed and widely applied in the environmental area. However, the algae removal efficiency of MOFs, the effect of metal ions and organic ligands contained in MOFs and the stability of MOFs in water need further study. Based on the characteristics of algae, five types of MOFs, which were Cu-MOF-74, Zn-MOF-74, ZIF-8, Ag/AgCl@ZIF-8 and MIL-125(Ti) were synthesized and characterized by X-ray diffractometer (XRD), field emission scanning electron microscope (FESEM), and X-ray photoelectron spectroscopy (XPS). The effect of MOFs on the growth of Microcystis aeruginosa was comparatively studied, and the inhibition mechanism of MOFs on algae as well as the stability of MOFs was explored. Results showed that all of the as-synthetic MOFs had superior stability in water, and the order of stability of MOFs followed the order MIL-125(Ti) > Cu-MOF-74 > Ag/AgCl@ZIF-8 > ZIF-8 > Zn-MOF-74. The types of metal ions and organic ligands doped in MOFs have grade affected the inhibitory efficiency on the algae: containing Cu2+ and Ag+ ions, MOFs had more significant inhibitory capacity to algae than those containing Zn2+ ions; meanwhile, compared with MOFs which are assembled with 2,5-dihydroxyterephthalic acid (DHTA) organic ligands, MOFs containing 2-methylimidazole (GC) organic contributed to the removal of algae significantly. The order of inhibitory effects of algae by five MOFs follows the order Cu-MOF-74 > Ag/AgCl@ZIF-8 > ZIF-8 > Zn-MOF-74 > MIL-125(Ti). The physiological characteristics of algal cells were changed after being treated with different concentrations of Cu-MOF-74. Once the concentration of Cu-MOF-74 reached 1 mg L-1, the algal cells began to be inhibited, the relative inhibition rate of algal cells at 120 h was over 400%, and the inhibition process fitted pseudo-second-order kinetic model well. The Cu2+ released by Cu-MOF-74 that the concentration higher than 1 mg L-1 would lead to the destruction of algae cell morphology and the loss of cell integrity, causing cell contents to be partially released into the water, promoting the accumulation and precipitation of algal cells which were destabilizing already to achieve the purpose of inhibition of algae. In summary, MOFs can be used to inhibit the growth of cyanobacteria and have a promising application prospect.

Dataset Information

Quantifying Ligand Binding to the Surface of Metal-Organic Frameworks.

Publications

Quantifying Ligand Binding to the Surface of Metal-Organic Frameworks.

Similar Datasets

OmicsDI is part of the ELIXIR infrastructure

Tweets