Ontology highlight
ABSTRACT:
SUBMITTER: Kim A
PROVIDER: S-EPMC10485016 | biostudies-literature | 2023 Sep
REPOSITORIES: biostudies-literature
Nature communications 20230907 1
As the complexity of organic molecules utilized by mankind increases, the phenomenon of atropisomerism is more frequently encountered. While a variety of well-established methods enable the control of a stereogenic center, a catalytic method for controlling a stereogenic axis in one substrate is typically unavailable for controlling axial chirality in other substrates with a similar structure. Herein, we report o-amidobiaryl as a flexible platform for chiral phosphoric acid-catalyzed atroposelec ...[more]