Ontology highlight
ABSTRACT:
SUBMITTER: Marinho TV
PROVIDER: S-EPMC10523436 | biostudies-literature | 2023 Sep
REPOSITORIES: biostudies-literature
Marinho Thompson V TV Schreiber Eric E Garwick Rachel E RE Brennessel William W WW Matson Ellen M EM
Inorganic chemistry 20230915 38
We present the post-synthetic modification of a polyoxovanadate-alkoxide (POV-alkoxide) cluster via the reactivity of its cationic form, [V<sub>6</sub>O<sub>7</sub>(OCH<sub>3</sub>)<sub>12</sub>]<sup>1+</sup>, with water. This result indicates that cluster oxidation increases the lability of bridging methoxide ligands, affording a ligand exchange reaction that serves to compensate for the increased charge of the cluster core. This synthetic advance affords the isolation of a series of POV-alkoxi ...[more]