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A novel method for extracting metals from asteroids using non-aqueous deep eutectic solvents.

ABSTRACT: Extra-terrestrial mining and metal processing are vital for access to strategic metals for space exploration. This study demonstrates for the first time the catalytic dissolution of metals from meteorite proxies of metal-rich asteroids using a deep eutectic solvent (DES). DESs are of particular interest for extra-terrestrial mining as they can be designed to have relatively low vapour pressures and could potentially be made from organic waste products created in extra-terrestrial settlements. Three types of meteorites were investigated: two chondrites (H3, H5) and one iron (IAB-MG) meteorite. Chondrite samples were composed of silicates (olivine, pyroxene) with metal-rich phases occurring as native metal alloys, sulphides and oxides. Metallic Fe-Ni and troilite (FeS) are the most abundant metal-bearing phases in all three samples, particularly in the iron-rich meteorite. The samples were subjected to chemical micro-etching experiments with iodine and iron(III) chloride as oxidising agents in a DES formed from the mixture of choline chloride and ethylene glycol. Micro-etching experiments demonstrated that Fe-Ni rich phases are effectively leached out in this system, while other mineral phases remain unreactive.

SUBMITTER: Rivera RM

PROVIDER: S-EPMC10560668 | biostudies-literature | 2023 Oct

REPOSITORIES: biostudies-literature

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A novel method for extracting metals from asteroids using non-aqueous deep eutectic solvents.

Rivera Rodolfo Marin RM Bird Philip P Jenkin Gawen R T GRT Abbott Andrew P AP

Scientific reports 20231008 1

Extra-terrestrial mining and metal processing are vital for access to strategic metals for space exploration. This study demonstrates for the first time the catalytic dissolution of metals from meteorite proxies of metal-rich asteroids using a deep eutectic solvent (DES). DESs are of particular interest for extra-terrestrial mining as they can be designed to have relatively low vapour pressures and could potentially be made from organic waste products created in extra-terrestrial settlements. Th ...[more]

PMID: 37807021

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Project description:This work presents the first validated method to analyze metals dissolved in deep eutectic solvents (DES) on a microwave plasma atomic emission spectrometer (MP-AES), which is key to the success of the upcoming field of solvometallurgical processing. The method was developed and validated for eleven metals: alkali metals: lithium (Li); alkaline earth metals: magnesium (Mg); transition metals: iron (Fe), cobalt (Co), nickel (Ni), copper (Cu), zinc (Zn), palladium (Pd); and post-transition metals: aluminum (Al), tin (Sn), and lead (Pb) in choline chloride based DES. The proposed method was validated with respect to linearity, limit of detection (LOD), limit of quantification (LOQ), accuracy, precision, and selectivity. Our method's selectivity was evaluated for three DES matrices: (1) choline chloride: ethylene glycol, (2) choline chloride: levulinic acid, and (3) choline chloride: ethylene glycol in the presence of iodine, which is an oxidant often used in solvometallurgy. In all three matrices, the linearity range was plotted with at least 5 levels of standard solutions. All the parameters satisfied the acceptability criteria suggested by international organizations, such as the International Council for Harmonization, AOAC International, and the International Union of Pure and Applied Chemistry. Specifically, the calculated LOD and LOQ are comparable with aqueous matrices on MP-AES and with other analytical methods. The metal with the lowest reported LOD (0.003 ppm) and LOQ (0.008 ppm) was Cu, while the highest LOD and LOQ were obtained for Mg at 0.07 and 0.22 ppm, respectively. The recovery and precision for the three DES matrices were acceptable, i.e., between 95.67-108.40% and less than 10%, respectively. Finally, to compare the proposed method with the standard analytical method used to measure metals dissolved in aqueous solutions, we used 2 ppm standard solutions in DES and found that the accuracy was unacceptable without using the proposed method. Therefore, it is evident that our method will be pivotal in the field of solvometallurgy, as it will allow accurate and precise detection and quantification of metals dissolved in DES and eliminate quantification errors, which were estimated in excess of 140% without using the method developed and proper DES matrix-matched calibrations.

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A novel method for extracting metals from asteroids using non-aqueous deep eutectic solvents.

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A novel method for extracting metals from asteroids using non-aqueous deep eutectic solvents.

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