Facile Route to Achieve a Hierarchical CuO/Nickel-Cobalt-Sulfide Electrode for Energy Storage
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PROVIDER: S-EPMC10672988 | biostudies-literature | 2023 Nov
REPOSITORIES: biostudies-literature
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Project description:Herein, a scalable electrodeposition strategy is proposed to achieve hierarchical CuO/nickel-cobalt-sulfide (NCS) electrodes using two-step potentiostatic deposition followed by high-temperature calcination. The introduction of CuO provides support for the further deposition of NSC to ensure a high load of active electrode materials, thus generating more abundant active electrochemical sites. Meanwhile, dense deposited NSC nanosheets are connected to each other to form many chambers. Such a hierarchical electrode prompts a smooth and orderly transmission channel for electron transport, and reserves space for possible volume expansion during the electrochemical test process. As a result, the CuO/NCS electrode exhibits superior specific capacitance (Cs) of 4.26 F cm-2 at 20 mA cm-2 and remarkable coulombic efficiency of 96.37%. Furthermore, the cycle stability of the CuO/NCS electrode remains at 83.05% within 5000 cycles. The multistep electrodeposition strategy provides a basis and reference for the rational design of hierarchical electrodes to be applied in the field of energy storage.
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Project description:A flexible wearable electrode consisting of nickel-cobalt sulfide (NCS) nanowires was fabricated in this study. Self-supporting NCS was grown in situ on porous carbon nanofibers without a binder as a novel material for supercapacitor electrodes. The NCS nanowires were grown using cyclic voltammetry electrodeposition, which proved to be a fast and environmentally friendly method with good controllability of the material structure. One-dimensional carbon nanofibers (C) have high surface-area-to-volume ratios, short ion transmission distances, excellent mechanical strengths, and remarkable flexibilities. Moreover, the NCS@C flexible electrode exhibited a synergetic effect with the active compounds, and the dense active sites were uniformly distributed across the entire surface of the carbon fibers, enabling rapid electron transport and enhancing the electrochemical properties of the NCS@C nanowires. The NCS@C achieved specific capacitances of 334.7 and 242.0 mAh g-1 at a current density of 2 A g-1 and high current densities (up to 40 A g-1), respectively, corresponding to a 72.3% retention rate. An NCS@C-nanofilm-based cathode and an activated-carbon-based anode were used to fabricate a flexible asymmetric supercapacitor. The device exhibited high energy and power densities of 12.91 Wh kg-1 and 358 W kg-1, respectively.
| S-EPMC10511439 | biostudies-literature
Project description:In the present work, we report the successful fabrication of dandelion-like Nickel-Cobalt Sulfide@Polypyrrole microspheres through the hydrothermal method and its possible application as a binder-free electrode in supercapacitors. This electrode exhibited low charge transfer resistance with a remarkable specific capacitance of 2554.9 F g-1 at 2.54 A g-1, in addition to considerable cycle life stability. Also, an asymmetric device was prepared using NiCo2S4@PPy/NF as positive and rGO/NF as negative electrodes. This asymmetric supercapacitor exhibited a specific capacitance of 98.9 F g-1 at 1.84 A g-1 and delivered an energy density of 35.17 Wh kg-1 at a power density of 1472 W kg-1. Such a remarkable performance can be originated from the synergy effect of NiCo2S4 and PPy and the direct deposition of the composite on the current collector. Our findings suggest the dandelion-like NiCo2S4@PPy as a promising material for making high-performance supercapacitors.
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Project description:A polypyrrole-cobalt sulfide composite counter electrode (CE) was prepared in this work. Firstly, polypyrrole (PPy) nanorods were prepared by an in situ polymerization method on FTO, then cobalt sulfide (CoS) nanoparticles were coated on PPy nanorods by the electrodeposition method. The DSSC with PPy-CoS CE exhibits superior photoelectric conversion efficiency than that based on platinum (Pt, one of common counter electrodes), which is 7.52%, improving more than 20% compared to Pt CE (6.19%). In addition, cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS) measurements demonstrated that the PPy-CoS CE exhibited excellent catalytic performance for I3 -/I- solution.
| S-EPMC9044837 | biostudies-literature
Project description:Metal sulfides are commonly used in energy storage and electrocatalysts due to their redox centers and active sites. Most literature reports show that their performance decreases significantly caused by oxidation in alkaline electrolyte during electrochemical testing. Herein, S and N co-doped graphene-based nickel cobalt sulfide aerogels are synthesized for use as rechargeable alkaline battery electrodes and oxygen reduction reaction (ORR) catalysts. Notably, this system shows improved cyclability due to the stabilization effect of the S and N co-doped graphene aerogel (SNGA). This reduces the rate of oxidation and the decay of electronic conductivity of the metal sulfides materials in alkaline electrolyte, i.e., the capacity decrease of CoNi2S4/SNGA is 4.2% for 10 000 cycles in a three-electrode test; the current retention of 88.6% for Co-S/SNGA after 12 000 s current-time chronoamperometric response in the ORR test is higher than corresponding Co-S nanoparticles and Co-S/non-doped graphene aerogels. Importantly, the results here confirm that the Ni-Co-S ternary materials behave as an electrode for rechargeable alkaline batteries rather than supercapacitors electrodes in three-electrode test as commonly described and accepted in the literature. Furthermore, formulas to evaluate the performance of hybrid battery devices are specified.
| S-EPMC5238742 | biostudies-literature
Project description:Transition-metal sulfides exaggerate higher theoretical capacities and were considered a type of prospective nanomaterials for energy storage; their inherent weaker conductivities and lower electrochemical active sites limited the commercial applications of the electrodes. The sheet-like nickel cobalt sulfide nanoparticles with richer sulfur vacancies were fabricated by a two-step hydrothermal technique. The sheet-like nanoparticles self-combination by ultrathin nanoparticles brought active electrodes entirely contacted with the electrolytes, benefiting ion diffusion and charges/discharges. Nevertheless, defect engineers of sulfur vacancy at the atomic level raise the intrinsic conductivities and improve the active sites for energy storage functions. As a result, the gained sulfur-deficient NiCo2S4 nanosheets consist of good specific capacitances of 971 F g-1 at 2 A g-1 and an excellent cycle span, retaining 88.7% of the initial capacitance over 3500 cyclings. Moreover, the values of capacitance results exhibited that the fulfilling characteristic of the sample was a combination of the hydrothermal procedure and the surface capacitances behavior. This novel investigation proposes a new perspective to importantly improve the electrochemical performances of the electrode by the absolute engineering of defects and morphologies in the supercapacitor field.
| S-EPMC9658846 | biostudies-literature
Project description: Not available
| S-EPMC10933289 | biostudies-literature
Project description:Transition metal oxides (TMOs) with spinel structures have a promising potential as the electrode materials for supercapacitors application owning to its outstanding theoretical capacity, good redox activity, and eco-friendly feature. In this work, MnCo2O4.5@NiCo2O4 nanowire composites for supercapacitors has been successfully fabricated by using a mild hydrothermal approach without any surfactant. The morphology and physicochemical properties of the prepared products can be well-controlled by adjusting experimental parameters of preparation. The double spinel composite exhibits a high specific capacitance of 325 F g-1 (146 C g-1) and 70.5% capacitance retention after 3,000 cycling tests at 1 A g-1.
| S-EPMC6344439 | biostudies-literature
Project description:Graphene and its composite hydrogels with interconnected three-dimensional (3D) structure have raised continuous attention in energy storage. Herein, we describe a simple hydrothermal strategy to synthesize 3D CoS/graphene composite hydrogel (CGH), which contains the reduction of GO sheets and anchoring of CoS nanoparticles on graphene sheets. The formed special 3D structure endows this composite with high electrochemical performance. Remarkably, the obtained 3D CGH exhibits high specific capacitance (C(s)) of 564 F g(-1) at a current density of 1 A g(-1) (about 1.3 times higher than pure CoS), superior rate capability and high stability. It is worth mentioning that this methodology is readily adaptable to decorating CoS nanoparticles onto graphene sheets and may be extended to the preparation of other pseudocapacitive materials based on graphene hydrogels for electrochemical applications.
| S-EPMC4754945 | biostudies-literature
Project description:In our research, a two-step solid-liquid route was employed to fabricate flowery nickel-cobalt hydroxide with sulphur ion grafting (Ni1Co2-S). The utilization of NaOH/agar and Na2S/agar could efficiently retard the release rates of OH- or S2- ions at the solid-liquid interface due to strong bonding between agar hydrogel and these anions. Ni1Co2-S generally displays ultrathin flowery micro-frame, ultrathin internal nanosheets and expanded pore size. Besides, the introduction of suitable sulphide species into nickel-cobalt hydroxide could improve its conductivity due to the lower band gap of Ni-Co sulphide. The supercapacitive electrode Ni1Co2-S presented capacitance of 1317.8 F g-1 (at 1 A g-1) and suitable rate performance (77.9% at 10 A g-1 and 59.3% at 20 A g-1). Furthermore, a hybrid supercapacitor (HSC) was developed utilizing positive Ni1Co2-S and negative activated carbon electrodes. As expected, the HSC device exhibited excellent specific capacitance (117.1 F g-1 at 1 A g-1), considerable energy densities (46.7 W h kg-1 at 0.845 kW kg-1 and 27.5 W h kg-1 even at 9 kW kg-1) and suitable cycling performance, which further illuminated the high energy storage capacity of Ni1Co2-S.
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