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ABSTRACT:
SUBMITTER: Willis OG
PROVIDER: S-EPMC10683000 | biostudies-literature | 2023 Nov
REPOSITORIES: biostudies-literature
Willis Oliver G OG Petri Filippo F De Rosa Davide F DF Mandoli Alessandro A Pal Robert R Zinna Francesco F Di Bari Lorenzo L
Journal of the American Chemical Society 20231108 46
We report the synthesis of chiral lanthanide complexes with extended π conjugation for efficient circularly polarized luminescence (CPL) via two-photon excitation (2PE). The pyridine bis-oxazoline (PyBox) core provides the chiral Ln<sup>3+</sup> environment, while the extension of the conjugated backbone through the pyridine 4-position with a phenylacetylene unit increases the two-photon absorption cross section. This work presents an important step toward the development of chiral systems displ ...[more]