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ABSTRACT:
SUBMITTER: Battistin F
PROVIDER: S-EPMC10848200 | biostudies-literature | 2024 Feb
REPOSITORIES: biostudies-literature
Battistin Federica F Bolliger Robin R Besmer Manuel Luca ML Fox Thomas T Blacque Olivier O Braband Henrik H Alberto Roger R
Inorganic chemistry 20240122 5
Here, we present the light-driven reactions of [Re(η<sup>7</sup>-C<sub>7</sub>H<sub>7</sub>)(η<sup>5</sup>-C<sub>7</sub>H<sub>9</sub>)]<sup>+</sup> (<b>1</b><sup>+</sup>) with nitriles, phosphines, and isocyanides, which are added to <b>1</b><sup>+</sup> via a ring slippage of the tropylium cation from η<sup>7</sup> to η<sup>3</sup>, forming [Re(η<sup>3</sup>-C<sub>7</sub>H<sub>7</sub>)(η<sup>5</sup>-C<sub>7</sub>H<sub>9</sub>)(L)<sub>2</sub>]<sup>+</sup> (L= acetonitrile <b>2</b><sup><b>+</b></ ...[more]