Ontology highlight
ABSTRACT:
SUBMITTER: Yin D
PROVIDER: S-EPMC10976361 | biostudies-literature | 2024 Mar
REPOSITORIES: biostudies-literature
Yin Dandan D Guo Yan Y Xu Tongyu T Ma Jiani J
ACS omega 20240311 12
The <i>thia</i>-Diels-Alder reaction represents a versatile synthetic method for the preparation of six-membered sulfur-containing compounds. However, the mechanism of the <i>thia</i>-Diels-Alder reactions remains unclear. In this work, time-resolved spectroscopic experiments and DFT calculations demonstrate that phenacyl sulfide undergoes Norrish II cleavage to produce thioaldehyde, and ortho-hydroxy benzhydryl alcohol occurs in a dehydration reaction to generate <i>o</i>-QMs using diphenylphos ...[more]