Dataset Information

Epitaxial Growth of Surface Perforations on Parallel Cylinders in Terraced Films of Block Copolymer/Homopolymer Blends.

ABSTRACT: Due to incommensurability between initial thickness and interdomain distance, thermal annealing inevitably produces relief surface terraces (islands and holes) of various morphologies in thin films of block copolymers. We have demonstrated three kinds of surface terraces in blend films: polygrain terraces with diffuse edges, polygrain terraces with step edges, and pseudo-monograin terraces with island coarsening. The three morphologies were obtained by three different thermal histories, respectively. The thermal histories were imposed on blend films, which were prepared by mixing a homopolystyrene (hPS, 6.1 kg/mol) with a weakly segregated, symmetry polystyrene-block poly(methyl methacrylate) (PS-b-PMMA, 42 kg/mol) followed by spin coating. At a given weight-fraction ratio of PS-b-PMMA/hPS = 75/25, the interior of the blend films forms parallel cylinders. Nevertheless, the surface of the blend films is always dominated by a skin layer of perforations, which epitaxially grow on top of parallel cylinders. By oxygen plasma etching at various time intervals to probe interior nanodomains, the epitaxial relationship between surface perforations and parallel cylinders has been identified by a scanning electron microscope.

SUBMITTER: Sun YS

PROVIDER: S-EPMC11008238 | biostudies-literature | 2024 Apr

REPOSITORIES: biostudies-literature

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Publications

Epitaxial Growth of Surface Perforations on Parallel Cylinders in Terraced Films of Block Copolymer/Homopolymer Blends.

Sun Ya-Sen YS Jian Yi-Qing YQ Yang Shin-Tung ST Wang Hsiao-Fang HF Junisu Belda Amelia BA Chen Chun-Yu CY Lin Jhih-Min JM

Langmuir : the ACS journal of surfaces and colloids 20240329 14

Due to incommensurability between initial thickness and interdomain distance, thermal annealing inevitably produces relief surface terraces (islands and holes) of various morphologies in thin films of block copolymers. We have demonstrated three kinds of surface terraces in blend films: polygrain terraces with diffuse edges, polygrain terraces with step edges, and pseudo-monograin terraces with island coarsening. The three morphologies were obtained by three different thermal histories, respecti ...[more]

PMID: 38551605

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Project description:Designing next-generation lightweight pulsed power devices hinges on understanding the factors influencing the energy storage performance of dielectric materials. Polymer dielectric films have a quadratic dependence of energy storage on the voltage breakdown strength, and strategies to enhance the breakdown strength are expected to yield a path toward high energy storage densities. Highly stratified lamellar block copolymer (L-BCP) films of model polystyrene-b-polymethylmethacrylate (PS-b-PMMA) exhibited as much as ~50% enhancement in breakdown voltage ( EBD ) (225% increase in stored energy density, U∼EBD2 ) compared to unordered as-cast L-BCP films. Such an energy density using amorphous polymer is on par with industry-standard semicrystalline biaxially oriented polypropylene (BOPP) and as such a notable development in the field. This work develops a deeper understanding of the molecular mechanisms of EBD enhancement in L-BCP films, relating EBD directly to molecular weight ( Mn ), with interpretation to effects of chain-end density and distribution, interface formation, layer thickness, and their relative contributions. As-cast disordered L-BCP films show decreasing EBD with decreasing Mn similar to homopolymer studies because of the increase of homogeneously distributed chain ends in the film. EBD increases significantly in parallel ordered L-BCP films because of the combination of interface formation and spatial isolation of the chain ends into segregated zones. We further confirm the role of chain ends in the breakdown process blending a low Mn L-BCP with matched Mn homopolymers to attain the same layer spacing as neat L-BCP of higher Mn . EBD shows a significant decrease at low homopolymer fractions because of increased net chain-end density within swollen ordered L-BCP domains in wet-brush regime, followed by increased EBD because of layer thickness increase via segregated "interphase layer" formation by excess homopolymers. Notably, EBD of homopolymer swollen L-BCPs is always lower than that of neat L-BCPs of the same domain spacing because of overall adverse chain-end contribution from homopolymers. These findings provide important selection rules for L-BCPs for designing next-generation flexible electronics with high energy density solid-state BCP film capacitors.

Dataset Information

Epitaxial Growth of Surface Perforations on Parallel Cylinders in Terraced Films of Block Copolymer/Homopolymer Blends.

Publications

Epitaxial Growth of Surface Perforations on Parallel Cylinders in Terraced Films of Block Copolymer/Homopolymer Blends.

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