Project description:As carbon nanotube (CNT) infused hybrid composites are increasingly identified as next-generation aerospace materials, it is vital to evaluate their long-term structural performance under aging environments. In this work, the durability of hierarchical, aligned CNT grafted aluminoborosilicate microfiber-epoxy composites (CNT composites) are compared against baseline aluminoborosilicate composites (baseline composites), before and after immersion in water at 25 °C (hydro) and 60 °C (hydrothermal), for extended durations (90 d and 180 d). The addition of CNTs is found to reduce water diffusivities by approximately 1.5 times. The mechanical properties (bending strength and modulus) and the damage sensing capabilities (DC conductivity) of CNT composites remain intact regardless of exposure conditions. The baseline composites show significant loss of strength (44 %) after only 15 d of hydrothermal aging. This loss of mechanical strength is attributed to fiber-polymer interfacial debonding caused by accumulation of water at high temperatures. In situ acoustic and DC electrical measurements of hydrothermally aged CNT composites identify extensive stress-relieving micro-cracking and crack deflections that are absent in the aged baseline composites. These observations are supported by SEM images of the failed composite cross-sections that highlight secondary matrix toughening mechanisms in the form of CNT pullouts and fractures which enhance the service life of composites and maintain their properties under accelerated aging environments.
Project description:Carbon fiber-reinforced polymer (CFRP) materials are widely used in aerospace and recreational equipment, but there is no efficient procedure for their end-of-life recycling. Ongoing work in the chemistry and engineering communities emphasizes recovering carbon fibers from such waste streams by dissolving or destroying the polymer binding. By contrast, our goal is to depolymerize amine-cured epoxy CFRP composites catalytically, thus enabling not only isolation of high-value carbon fibers, but simultaneously opening an approach to recovery of small molecule monomers that can be used to regenerate precursors to new composite resin. To do so will require understanding of the molecular mechanism(s) of such degradation sequences. Prior work has shown the utility of hydrogen peroxide as a reagent to affect epoxy matrix decomposition [1]. Herein we describe the chemical transformations involved in that sequence: the reaction proceeds by oxygen atom transfer to the polymer's linking aniline group, forming an N-oxide intermediate. The polymer is then cleaved by an elimination and hydrolysis sequence. We find that elimination is the slower step. Scandium trichloride is an efficient catalyst for this step, reducing reaction time in homogeneous model systems and neat cured matrix blocks. The conditions can be applied to composed composite materials, from which pristine carbon fibers can be recovered.
Project description:Sustainable natural fiber reinforced composites have attracted significant interest due to the growing environmental concerns with conventional synthetic fiber as well as petroleum-based resins. One promising approach to reducing the large carbon footprint of petroleum-based resins is the use of bio-based thermoset resins. However, current fiber-reinforced bio-based epoxy composites exhibit relatively lower mechanical properties such as tensile, flexural strength, and modulus, which limits their wider application. Here the fabrication of high-performance composites using jute fibers is reported, modified with graphene nanoplates (GNP) and graphene oxide (GO), and reinforced with bio-based epoxy resin. It is demonstrated that physical and chemical treatments of jute fibers significantly improve their fiber volume fraction (Vf) and matrix adhesion, leading to enhanced mechanical properties of the resulting Jute/Bio-epoxy (J/BE) composites. Furthermore, the incorporation of GNP and GO further increases the tensile and flexural strength of the J/BE composites. The study reveals the potential of graphene-based jute fiber-reinforced composites with bio-based epoxy resin as a sustainable and high-performance material for a wide range of applications. This work contributes to the development of sustainable composites that have the potential to reduce the negative environmental impact of conventional materials while also offering improved mechanical properties.
Project description:Carbon fiber (CF) is widely used in the preparation of carbon-fiber-reinforced polymer composites (CFRP) in which it is combined with epoxy resin due to its good mechanical properties. Thermosetting bisphenol A epoxy resin, as one of the most common polymer materials, is a non-renewable resource, leading to a heavy environmental burden and resource waste. To solve the above problems and achieve high mechanical and thermal properties comparable to those of bisphenol A, herein, a high-performance, degradable and recyclable bio-based epoxy resin was developed by reacting the lignin derivative vanillin with 4-amino cyclohexanol via Schiff base. This bio-based epoxy resin showed a Young's modulus of 2.68 GPa and tensile strength of 44 MPa, 36.8% and 15.8% higher than those of bisphenol A epoxy, respectively. Based on the reversible exchange reaction of the imine bond, the resin exhibited good degradation in an acidic environment and was recoverable by heat treatment. Moreover, the prepared epoxy resin could be used to prepare carbon fiber (CF)-reinforced composites. By washing off the epoxy resin, the carbon fiber could be completely recycled. The recovered carbon fiber was well preserved and could be used again for the preparation of composite materials to realize the complete recovery and utilization of carbon fiber. This study opens a way for the preparation of high-performance epoxy resin and the effective recycling of carbon fiber.
Project description:An eco-friendly epoxy/thiol-ene photopolymerization (ETEP) process was employed to prepare epoxy bio-composites using a commercial biobased epoxy resin and a woven jute fabric as reinforcement. In this process the components of the thiol-ene system, an allyl-functionalized ditertiary amine curing agent, a multifunctional thiol and a radical photoinitiator, were added to the epoxy resin to produce a polyether–polythioether crosslinked co-network. Moreover, the jute fibers were functionalized with thiol groups using the 3-mercaptopropyl (trimethoxysilane) with the purpose of creating a chemically bonded polymeric matrix/fiber system. The obtained bio-composites prepared with the thiol-functionalized cellulose fibers exhibited an increase up to 52% and 40% in flexural modulus and strength with respect to the non-functionalized counterparts. Under the three-point bending loadings, the composites displayed higher deformation at break and toughness due to the presence of polythioethers in the co-network. The prepared bio-composites developed in this work are excellent candidates to extend the use of cellulose fibers for structural applications.
Project description:This paper aims to assess experimentally the mechanical and tribological behavior of conventional and functionally graded (FG) polymeric matrix composites reinforced with continuous glass fibers. The small punch test (SPT) and a pin-on-disc device were used in the present work to examine the mechanical and wear behavior, respectively. The hand lay-up technique was used in the present investigation to manufacture the conventional and FG composites. Various wooden looms with different nailed spacing were employed to manufacture the FG composites. According to test type, the FG composite is composed of four and ten layers, with a different glass fiber volume of fraction (Vf%) for each layer. In addition, the finite element simulation based on Hashin's failure criterion and cohesive zone modeling was used to show the progressive failure and give more explanation regarding the flexural behavior of such composites. The present results indicate that the wear rate of an FG composite could be affected by many factors, including the disk speed, applied load, the composite layers number, and average glass fiber volume fraction. On the other hand, the arrangement of layers in the composite materials by variation of Vf% for each layer can improve the wear rate and value of the ultimate load before the fracture of the composite material when subjected to SPT. The experimental and numerical results for all SPT specimens showed that the fracture of the SPT specimens began beneath the punch tip and grew along the fiber direction. The ultimate flexural capacity of FG composites increased by 30% compared with the conventional composites.
Project description:Impregnation of expandable graphite (EG) after thermal treatment with an epoxy resin containing surface-active agents (SAAs) enhanced the intercalation of epoxy monomer between EG layers and led to further exfoliation of the graphite, resulting in stacks of few graphene layers, so-called "stacked" graphene (SG). This process enabled electrical conductivity of cured epoxy/SG composites at lower percolation thresholds, and improved thermo-mechanical properties were measured with either Kevlar, carbon or glass-fiber-reinforced composites. Several compositions with SAA-modified SG led to higher dynamic moduli especially at high temperatures, reflecting the better wetting ability of the modified nanoparticles. The hydrophilic/hydrophobic nature of the SAA dictates the surface energy balance. More hydrophilic SAAs promoted localization of the SG at the Kevlar/epoxy interface, and morphology seems to be driven by thermodynamics, rather than the kinetic effect of viscosity. This effect was less obvious with carbon or glass fibers, due to the lower surface energy of the carbon fibers or some incompatibility with the glass-fiber sizing. Proper choice of the surfactant and fine-tuning of the crosslink density at the interphase may provide further enhancements in thermo-mechanical behavior.
Project description:The mechanical properties of aerospace carbon fiber/graphene nanoplatelet/epoxy hybrid composites reinforced with pristine graphene nanoplatelets (GNP), highly concentrated graphene oxide (GO), and Functionalized Graphene Oxide (FGO) are investigated in this study. By utilizing molecular dynamics data from the literature, the bulk-level mechanical properties of hybrid composites are predicted using micromechanics techniques for different graphene nanoplatelet types, nanoplatelet volume fractions, nanoplatelet aspect ratios, carbon fiber volume fractions, and laminate lay-ups (unidirectional, cross-ply, and angle-ply). For the unidirectional hybrid composites, the results indicate that the shear and transverse properties are significantly affected by the nanoplatelet type, loading and aspect ratio. For the cross-ply and angle ply hybrid laminates, the effect of the nanoplate's parameters on the mechanical properties is minimal when using volume fractions and aspect ratios that are typically used experimentally. The results of this study can be used in the design of hybrid composites to tailor specific laminate properties by adjusting nanoplatelet parameters.
Project description:The low deposition time efficiency and small thickness limit the expansion of polydopamine (PDA) application to fiber-reinforced high-temperature ceramic composites. In this work, the electric field-assisted polymerization (EFAP) route was developed to improve the deposition time efficiency of PDA coating and overcome the thickness limitation. Carbonized polydopamine (C-PDA) coating was used as the interphase of carbon fiber-reinforced ZrB2-based composites (Cf/ZrB2-based composite) to bond rigid fibers and brittle ceramics, where C-PDA coating was prepared by the carbonization of PDA coating. Firstly, uniform and dense PDA coatings were deposited on carbon fibers (Cf) by EFAP. The thickness of PDA coating reached the micron level (over 1800 nm) for the first time. Benefiting from the EFAP route promoting the oxidation process of dopamine (DA) and accelerating the aggregation and in-situ polymerization of DA and its derivatives on the surface of Cf, the deposition rate of PDA coating reached 5589 nm/h, which was 3 orders of magnitude higher than that of the traditional self-polymerization process. By adjusting the EFAP parameters (e.g. DA-concentration, current, and deposition time), the thickness of PDA coating could be conveniently designed from nano-scale to micro-scale. Then, PDA coating was pyrolyzed to obtain C-PDA coating. C-PDA coating was well bonded on Cf without visible cross-sticking among neighboring fibers. C-PDA coating presented a layered structure and the thickness of C-PDA coating could be designed by controlling the thickness of PDA. C-PDA coating was used as the interfacial phase of the Cf/ZrB2-based composite, which ensured that the composite possessed good load-bearing capacity and thermal stability. Moreover, extraordinary damage resistance of the composite was achieved, with work of fracture up to 9936 ± 548 J/m2 at room temperature and 19,082 ± 3458 J/m2 at 1800 °C. The current work provides a high time efficiency processing route for depositing PDA coating on carbon fibers and demonstrates the attractive potential of PDA coating in fiber-reinforced high-temperature ceramic composites.
Project description:The antagonism between strength and corrosion resistance in graphene-reinforced aluminum matrix composites is an inherent challenge to designing reliable structural components. Heteroatom microstructural modification is highly appreciated to conquer the obstacle. Here, a bottom-up strategy to exploit the heterogeneous phase interface to enable high corrosion durability is proposed. Deformation-driven metallurgy derived from severe plastic deformation is developed to produce Mg-alloyed fluorinated graphene structures with homogeneous dispersion. These structures allow for absorbing corrosion products, forming a dense protective layer against corrosion, and local micro-tuning of the suppression of charge transfer. This results in superior corrosion resistance with an outstanding strength-ductility balance of the composites via ultrafine-grained and precipitation strengthening. The anti-corrosion polarization resistance remains 89% of the initial state after 2-month immersion in chloride-containing environment, while the ultra-tensile strength and elongation of 532 ± 39 MPa and 17.3 ± 1.2% are obtained. The economical strategy of heteroatom modification broadens the horizon for anti-corrosion engineering in aluminum matrix composites, which is critical for the design of carbonaceous nanomaterial-reinforced composites to realize desired performances for practical applications.