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Coassembly of Complementary Polyhedral Metal-Organic Framework Particles into Binary Ordered Superstructures.

ABSTRACT: Here we report the formation of a 3D NaCl-type binary porous superstructure via coassembly of two colloidal polyhedral metal-organic framework (MOF) particles having complementary sizes, shapes, and charges. We employed a polymeric-attenuated Coulombic self-assembly approach, which also facilitated the coassembly of these MOF particles with spherical polystyrene particles to form 2D binary superstructures. Our results pave the way for using MOFs to create sophisticated superstructures comprising particles of various sizes, shapes, porosities, and chemical compositions.

SUBMITTER: Meng L

PROVIDER: S-EPMC11311218 | biostudies-literature | 2024 Aug

REPOSITORIES: biostudies-literature

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Coassembly of Complementary Polyhedral Metal-Organic Framework Particles into Binary Ordered Superstructures.

Meng Lingxin L Fonseca Javier J Sánchez-Naya Roberto R Ghadiri Amir Mohammad AM Imaz Inhar I Maspoch Daniel D

Journal of the American Chemical Society 20240726 31

Here we report the formation of a 3D NaCl-type binary porous superstructure <i>via</i> coassembly of two colloidal polyhedral metal-organic framework (MOF) particles having complementary sizes, shapes, and charges. We employed a polymeric-attenuated Coulombic self-assembly approach, which also facilitated the coassembly of these MOF particles with spherical polystyrene particles to form 2D binary superstructures. Our results pave the way for using MOFs to create sophisticated superstructures com ...[more]

PMID: 39058575

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