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ABSTRACT:
SUBMITTER: Grechi C
PROVIDER: S-EPMC11356967 | biostudies-literature | 2024 Aug
REPOSITORIES: biostudies-literature
Grechi Cristian C Carlotto Silvia S Guelfi Massimo M Samaritani Simona S Armelao Lidia L Labella Luca L
Molecules (Basel, Switzerland) 20240820 16
Sandwich d/f heterometallic complexes [(Ln(hfac)<sub>3</sub>)<sub>2</sub>M(acac)<sub>3</sub>] (Ln = La, Pr, Sm, Dy and M = Co; Ln = La and M = Ru) were prepared in strictly anhydrous conditions reacting the formally unsaturated fragment [Ln(hfac)<sub>3</sub>] and [M(acac)<sub>3</sub>] in a 2-to-1 molar ratio. These heterometallic complexes are highly sensitive to moisture. Spectroscopic observation revealed that on hydrolysis, these compounds yield dinuclear heterometallic compounds [Ln(hfac)<su ...[more]