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Hydrogen bonding and perhalometallate ions: a supramolecular synthetic strategy for new inorganic materials.

ABSTRACT: A synthetic strategy for constructing ionic hydrogen-bonded materials by combining perhalometallate anions with cations able to serve as hydrogen bond donors is presented. The approach is based on identification of well defined hydrogen bond acceptor sites on the anions by a combination of experimental and theoretical approaches. Selective population of these sites by hydrogen bond donors has the potential to afford organized crystalline arrays in one, two, or three dimensions. The approach is applicable to a wide range of metal centers.

SUBMITTER: Brammer L

PROVIDER: S-EPMC122702 | biostudies-literature | 2002 Apr

REPOSITORIES: biostudies-literature

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Hydrogen bonding and perhalometallate ions: a supramolecular synthetic strategy for new inorganic materials.

Brammer Lee L Swearingen John K JK Bruton Eric A EA Sherwood Paul P

Proceedings of the National Academy of Sciences of the United States of America 20020401 8

A synthetic strategy for constructing ionic hydrogen-bonded materials by combining perhalometallate anions with cations able to serve as hydrogen bond donors is presented. The approach is based on identification of well defined hydrogen bond acceptor sites on the anions by a combination of experimental and theoretical approaches. Selective population of these sites by hydrogen bond donors has the potential to afford organized crystalline arrays in one, two, or three dimensions. The approach is a ...[more]

PMID: 11959946

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