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Directed reduction of beta-amino ketones to syn or anti 1,3-amino alcohol derivatives.


ABSTRACT: [reaction: see text] The reduction of beta-amino ketones with samarium(II) iodide has been investigated. Either the syn or anti 1,3-amino alcohols can be obtained as the major product due to a divergence in selectivity with different N-protecting groups.

SUBMITTER: Keck GE 

PROVIDER: S-EPMC1480404 | biostudies-literature | 2002 Sep

REPOSITORIES: biostudies-literature

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Directed reduction of beta-amino ketones to syn or anti 1,3-amino alcohol derivatives.

Keck Gary E GE   Truong Anh P AP  

Organic letters 20020901 18


[reaction: see text] The reduction of beta-amino ketones with samarium(II) iodide has been investigated. Either the syn or anti 1,3-amino alcohols can be obtained as the major product due to a divergence in selectivity with different N-protecting groups. ...[more]

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