Unknown

Dataset Information

0

Reaction of benzoxasilocines with aromatic aldehydes: Synthesis of homopterocarpans.


ABSTRACT: Condensation of 2H-benzo[g][1,2]oxasilocines with aromatic aldehydes in the presence of boron trifluoride affords mixtures of cis/trans 2-phenyl-3-vinylchromans with moderate yields. These can be transformed into homopterocarpans, a synthetic group of substances homologous to the natural isoflavonoid pterocarpans.

SUBMITTER: Alvarez-Corral M 

PROVIDER: S-EPMC1810298 | biostudies-literature | 2007 Feb

REPOSITORIES: biostudies-literature

altmetric image

Publications

Reaction of benzoxasilocines with aromatic aldehydes: Synthesis of homopterocarpans.

Alvarez-Corral Míriam M   López-Sánchez Cristóbal C   Jiménez-González Leticia L   Rosales Antonio A   Muñoz-Dorado Manuel M   Rodríguez-García Ignacio I  

Beilstein journal of organic chemistry 20070208


Condensation of 2H-benzo[g][1,2]oxasilocines with aromatic aldehydes in the presence of boron trifluoride affords mixtures of cis/trans 2-phenyl-3-vinylchromans with moderate yields. These can be transformed into homopterocarpans, a synthetic group of substances homologous to the natural isoflavonoid pterocarpans. ...[more]

Similar Datasets

| S-EPMC6644805 | biostudies-literature
| S-EPMC3896266 | biostudies-literature
| S-EPMC6766844 | biostudies-other
| S-EPMC7671204 | biostudies-literature
| S-EPMC5510876 | biostudies-other
| S-EPMC3511020 | biostudies-literature
| S-EPMC5990813 | biostudies-literature
| S-EPMC2906238 | biostudies-literature
| S-EPMC4281267 | biostudies-literature
| S-EPMC4120972 | biostudies-literature