Generation of pyridyl coordinated organosilicon cation pool by oxidative Si-Si bond dissociation.
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ABSTRACT:
SUBMITTER: Nokami T
PROVIDER: S-EPMC1810300 | biostudies-literature | 2007 Feb
REPOSITORIES: biostudies-literature
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Generation of pyridyl coordinated organosilicon cation pool by oxidative Si-Si bond dissociation.
Nokami Toshiki T Soma Ryoji R Yamamoto Yoshimasa Y Kamei Toshiyuki T Itami Kenichiro K Yoshida Jun-Ichi J
Beilstein journal of organic chemistry 20070208
An organosilicon cation stabilized by intramolecular pyridyl coordination was effectively generated and accumulated by oxidative Si-Si bond dissociation of the corresponding disilane using low temperature electrolysis, and was characterized by NMR and CSI-MS. ...[more]
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