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Experimental observation of quantum oscillation of surface chemical reactivities.


ABSTRACT: Here we present direct observation of a quantum reactivity with respect to the amounts of O(2) adsorbed and the rates of surface oxidation as a function of film thickness on ultrathin (2-6 nm) Pb mesas by scanning tunneling microscopy. Simultaneous spectroscopic measurements on the electronic structures reveal a quantum oscillation that originates from quantum well states of the mesas, as a generalization of the Fabry-Pérot modes of confined electron waves. We expect the quantum reactivity to be a general phenomenon for most ultrathin metal films with broad implications, such as nanostructure tuning of surface reactivities and rational design of heterogeneous catalysts.

SUBMITTER: Ma X 

PROVIDER: S-EPMC1874227 | biostudies-literature |

REPOSITORIES: biostudies-literature

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