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A novel approach to phosphonic acids from hypophosphorous acid.


ABSTRACT: A novel access to phosphonic acids via Pd-catalyzed tandem carbon-phosphorus bond formation - oxidation processes was developed. The procedures involve atom-economical and environmentally friendly functionalization reactions of hypophosphorous acid (H(3)PO(2)) and H-phosphinic acids [RP(O)(OH)(H)].

SUBMITTER: Bravo-Altamirano K 

PROVIDER: S-EPMC2031837 | biostudies-literature | 2007 Aug

REPOSITORIES: biostudies-literature

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A novel approach to phosphonic acids from hypophosphorous acid.

Bravo-Altamirano Karla K   Montchamp Jean-Luc JL  

Tetrahedron letters 20070801 33


A novel access to phosphonic acids via Pd-catalyzed tandem carbon-phosphorus bond formation - oxidation processes was developed. The procedures involve atom-economical and environmentally friendly functionalization reactions of hypophosphorous acid (H(3)PO(2)) and H-phosphinic acids [RP(O)(OH)(H)]. ...[more]

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