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Solvent-controlled regioselective protection of allyl-4,6-benzylidene glucopyranosides.

ABSTRACT: We wish to report a simple synthetic procedure, which permits the regiospecific mono-acylation, alkylation and silylation at the 2-position of allyl 4,6-O-benzylidene alpha-D-glucopyranoside in high yields and which does not require the use of catalysts.

SUBMITTER: Ness KA

PROVIDER: S-EPMC2048501 | biostudies-literature | 2007 Sep

REPOSITORIES: biostudies-literature

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Solvent-controlled regioselective protection of allyl-4,6-benzylidene glucopyranosides.

Ness Kerry Ann KA Migaud Marie E ME

Beilstein journal of organic chemistry 20070926

We wish to report a simple synthetic procedure, which permits the regiospecific mono-acylation, alkylation and silylation at the 2-position of allyl 4,6-O-benzylidene alpha-D-glucopyranoside in high yields and which does not require the use of catalysts. ...[more]

PMID: 17897436

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Orthogonal protection of saccharide polyols through solvent-free one-pot sequences based on regioselective silylations.

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