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O2 chemistry of dicopper complexes with alkyltriamine ligands. Comparing synergistic effects on O2 binding.

ABSTRACT: Two dicopper(I) complexes containing tertiary N-methylated hexaaza ligands which impose different steric constraints to the Cu ions have been synthesized, and their reactivity toward O2 has been compared with a mononuclear related system, highlighting the importance of cooperative effects between the metal centers in O2 activation.

SUBMITTER: Company A 

PROVIDER: S-EPMC2526348 | biostudies-literature | 2006 Jul

REPOSITORIES: biostudies-literature

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O2 chemistry of dicopper complexes with alkyltriamine ligands. Comparing synergistic effects on O2 binding.

Company Anna A   Lamata Diana D   Poater Albert A   Solà Miquel M   Rybak-Akimova Elena V EV   Que Lawrence L   Fontrodona Xavier X   Parella Teodor T   Llobet Antoni A   Costas Miquel M  

Inorganic chemistry 20060701 14

Two dicopper(I) complexes containing tertiary N-methylated hexaaza ligands which impose different steric constraints to the Cu ions have been synthesized, and their reactivity toward O2 has been compared with a mononuclear related system, highlighting the importance of cooperative effects between the metal centers in O2 activation. ...[more]

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