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Catalytic enantioselective hetero-Diels-Alder reactions of an azo compound.


ABSTRACT: This communication describes studies in which an azo hetero-Diels-Alder adduct was furnished in high regio- and enantioselectivity using azopyridine as a reagent and silver as a catalyst. The obtained hetero-Diels-Alder adduct was easily converted to the corresponding chiral 1,4-diamino alcohol.

SUBMITTER: Kawasaki M 

PROVIDER: S-EPMC2546566 | biostudies-literature | 2006 Dec

REPOSITORIES: biostudies-literature

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Catalytic enantioselective hetero-Diels-Alder reactions of an azo compound.

Kawasaki Masanori M   Yamamoto Hisashi H  

Journal of the American Chemical Society 20061201 51


This communication describes studies in which an azo hetero-Diels-Alder adduct was furnished in high regio- and enantioselectivity using azopyridine as a reagent and silver as a catalyst. The obtained hetero-Diels-Alder adduct was easily converted to the corresponding chiral 1,4-diamino alcohol. ...[more]

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