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Palladium asymmetric allylic alkylation of prochiral nucleophiles: horsfiline.

ABSTRACT: [reaction; see text] The asymmetric synthesis of the oxindole alkaloid horsfiline is described. A palladium-catalyzed asymmetric allylic alkylation (AAA) is used to set the spiro(pyrrolidine-oxindole) stereogenic center.

SUBMITTER: Trost BM 

PROVIDER: S-EPMC2565574 | biostudies-literature | 2006 May

REPOSITORIES: biostudies-literature

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Palladium asymmetric allylic alkylation of prochiral nucleophiles: horsfiline.

Trost Barry M BM   Brennan Megan K MK  

Organic letters 20060501 10

[reaction; see text] The asymmetric synthesis of the oxindole alkaloid horsfiline is described. A palladium-catalyzed asymmetric allylic alkylation (AAA) is used to set the spiro(pyrrolidine-oxindole) stereogenic center. ...[more]

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