Ontology highlight
ABSTRACT:
SUBMITTER: Huang W
PROVIDER: S-EPMC2575851 | biostudies-literature | 2008 Jan
REPOSITORIES: biostudies-literature
Huang Wenlin W Schopfer Mark M Zhang Cheng C Howell Robertha C RC Todaro Louis L Gee Becky A BA Francesconi Lynn C LC Polenova Tatyana T
Journal of the American Chemical Society 20071221 2
Paramagnetic rare-earth elements have been examined as NMR structural probes in polyoxoanionic solids, which have a variety of applications as luminescent materials that are usually disordered and therefore intractable by traditional structural methods. Thirteen Keggin and Wells-Dawson polyoxotungstates containing substitutions with lanthanides of different effective magnetic moments have been examined by 31P magic angle spinning NMR spectroscopy. The electron-nuclear dipolar interaction dominat ...[more]