Ontology highlight
ABSTRACT:
SUBMITTER: Zhu H
PROVIDER: S-EPMC2585038 | biostudies-literature | 2008 Aug
REPOSITORIES: biostudies-literature
Zhu Heng H Coleman Donna M DM Dehen Christopher J CJ Geisler Iris M IM Zemlyanov Dmitry D Chmielewski Jean J Simpson Garth J GJ Wei Alexander A
Langmuir : the ACS journal of surfaces and colloids 20080711 16
Dithiocarbamates (DTCs) can be formed by the in situ condensation of polar alkylamines with CS 2, and assembled into dithiocarbamate-anchored monolayers (DAMs) on Au substrates in aqueous solutions. Primary and secondary amines can both be used to prepare DTCs, but have significant differences in their reactivities and product stabilities. Ultraviolet absorption spectroscopy provides a convenient method for monitoring in situ DTC formation as well as the formation of potential byproducts. The ki ...[more]