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Regio- and stereoselective isomerizations of allenamides: synthesis of 2-amido-dienes and their tandem isomerization-electrocyclic ring-closure.

ABSTRACT: A regio- and stereoselective isomerization of allenamides is described, leading to preparations of de novo 2-amido-dienes and a tandem isomerization-6pi-electron electrocyclic ring-closure.

SUBMITTER: Hayashi R

PROVIDER: S-EPMC2732350 | biostudies-literature | 2009 May

REPOSITORIES: biostudies-literature

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Regio- and stereoselective isomerizations of allenamides: synthesis of 2-amido-dienes and their tandem isomerization-electrocyclic ring-closure.

Hayashi Ryuji R Hsung Richard P RP Feltenberger John B JB Lohse Andrew G AG

Organic letters 20090501 10

A regio- and stereoselective isomerization of allenamides is described, leading to preparations of de novo 2-amido-dienes and a tandem isomerization-6pi-electron electrocyclic ring-closure. ...[more]

PMID: 19371081

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