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Highly active and robust Cp* iridium complexes for catalytic water oxidation.

ABSTRACT: A series of Cp*Ir catalysts are the most active known by over an order of magnitude for water oxidation with Ce(IV). DFT calculations support a Cp*Ir=O complex as an active species.

SUBMITTER: Hull JF 

PROVIDER: S-EPMC2742501 | biostudies-literature | 2009 Jul

REPOSITORIES: biostudies-literature

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Highly active and robust Cp* iridium complexes for catalytic water oxidation.

Hull Jonathan F JF   Balcells David D   Blakemore James D JD   Incarvito Christopher D CD   Eisenstein Odile O   Brudvig Gary W GW   Crabtree Robert H RH  

Journal of the American Chemical Society 20090701 25

A series of Cp*Ir catalysts are the most active known by over an order of magnitude for water oxidation with Ce(IV). DFT calculations support a Cp*Ir=O complex as an active species. ...[more]

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