Highly active and robust Cp* iridium complexes for catalytic water oxidation.
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ABSTRACT:
SUBMITTER: Hull JF
PROVIDER: S-EPMC2742501 | biostudies-literature | 2009 Jul
REPOSITORIES: biostudies-literature
Publications
Highly active and robust Cp* iridium complexes for catalytic water oxidation.
Hull Jonathan F JF Balcells David D Blakemore James D JD Incarvito Christopher D CD Eisenstein Odile O Brudvig Gary W GW Crabtree Robert H RH
Journal of the American Chemical Society 20090701 25
A series of Cp*Ir catalysts are the most active known by over an order of magnitude for water oxidation with Ce(IV). DFT calculations support a Cp*Ir=O complex as an active species. ...[more]
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