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ABSTRACT:
SUBMITTER: Gutierrez O
PROVIDER: S-EPMC2751814 | biostudies-literature | 2009 Oct
REPOSITORIES: biostudies-literature
Gutierrez Osvaldo O Iafe Robert G RG Houk K N KN
Organic letters 20091001 19
The organocatalytic transfer hydrogenation reactions of 3-phenyl-2-cyclopentenone with imidazolidinone catalysts are evaluated using the hybrid density functional (B3LYP/6-31G(d)) theory. The origin of the preference for the (E) iminium transition state is determined, and the stereoselectivity of hydride transfer is investigated. ...[more]