Ontology highlight
ABSTRACT:
SUBMITTER: De Vries TS
PROVIDER: S-EPMC2752606 | biostudies-literature | 2009 Sep
REPOSITORIES: biostudies-literature
Journal of the American Chemical Society 20090901 36
The method of continuous variation in conjunction with (6)Li NMR spectroscopy was used to characterize lithium phenolates solvated by tetrahydrofuran and 1,2-dimethoxyethane. The strategy relies on the formation of ensembles of homo- and heteroaggregated phenolates. The symmetries and concentration dependencies of the heteroaggregates attest to the aggregation numbers of the homoaggregates. The structurally diverse phenols afford substrate- and solvent-dependent combinations of lithium phenolate ...[more]