Ontology highlight
ABSTRACT:
SUBMITTER: Morales A
PROVIDER: S-EPMC2770188 | biostudies-literature | 2008 Jun
REPOSITORIES: biostudies-literature
Morales Alexis A Weber Ralph T RT Melendez Enrique E
Applied organometallic chemistry 20080601 8
Host-guest interactions between α-, β-, and γ-cyclodextrins and vanadocene dichloride (Cp(2)VCl(2)) have been investigated by a combination of thermogravimetric analysis, differential scanning calorimeters, PXRD and solid state and solution EPR spectroscopy. The solid state results demonstrated that only β- and γ-cyclodextrins form 1:1 inclusion complexes, while α-cyclodextrin does not form an inclusion complex with Cp(2)VCl(2). The β- and γ-CD-Cp(2)VCl(2) inclusion complexes exhibited anisotrop ...[more]