Ontology highlight
ABSTRACT:
SUBMITTER: Pang K
PROVIDER: S-EPMC2777662 | biostudies-literature | 2009 Sep
REPOSITORIES: biostudies-literature
Pang Keliang K Figueroa Joshua S JS Tonks Ian A IA Sattler Wesley W Parkin Gerard G
Inorganica chimica acta 20090901 12
Nickel and palladium paddlewheel complexes that feature 2-mercapto-1-t-butylimidazolyl (mim(Bu(t) )) bridging ligands, namely Ni(2)[mim (Bu(t) )](4) and Pd(2)[mim (Bu(t) )](4), have been synthesized and structurally characterized by X-ray diffraction. Since the mim (Bu(t) ) ligand bridges in an asymmetric manner via a sulfur and nitrogen donor, paddlewheel compounds of the type M(2)[mim (Bu(t) )](4) may exist as isomers that are distinguished by the relative orientations of the ligands. In this ...[more]