Unknown

Dataset Information

0

2-Mercapto-1-t-butylimidazolyl as a Bridging Ligand: Synthesis and Structural Characterization of Nickel and Palladium Paddlewheel Complexes.


ABSTRACT: Nickel and palladium paddlewheel complexes that feature 2-mercapto-1-t-butylimidazolyl (mim(Bu(t) )) bridging ligands, namely Ni(2)[mim (Bu(t) )](4) and Pd(2)[mim (Bu(t) )](4), have been synthesized and structurally characterized by X-ray diffraction. Since the mim (Bu(t) ) ligand bridges in an asymmetric manner via a sulfur and nitrogen donor, paddlewheel compounds of the type M(2)[mim (Bu(t) )](4) may exist as isomers that are distinguished by the relative orientations of the ligands. In this regard, the (4,0)-Ni(2)[mim (Bu(t) )](4) and trans-(2,2)-Ni(2)[mim (Bu(t) )](4) isomers have been isolated for the nickel system, while the (4,0)-Pd(2)[mim (Bu(t) )](4) and (3,1)-Pd(2)[mim (Bu(t) )](4) isomers have been isolated for the palladium system.

SUBMITTER: Pang K 

PROVIDER: S-EPMC2777662 | biostudies-literature | 2009 Sep

REPOSITORIES: biostudies-literature

altmetric image

Publications

2-Mercapto-1-t-butylimidazolyl as a Bridging Ligand: Synthesis and Structural Characterization of Nickel and Palladium Paddlewheel Complexes.

Pang Keliang K   Figueroa Joshua S JS   Tonks Ian A IA   Sattler Wesley W   Parkin Gerard G  

Inorganica chimica acta 20090901 12


Nickel and palladium paddlewheel complexes that feature 2-mercapto-1-t-butylimidazolyl (mim(Bu(t) )) bridging ligands, namely Ni(2)[mim (Bu(t) )](4) and Pd(2)[mim (Bu(t) )](4), have been synthesized and structurally characterized by X-ray diffraction. Since the mim (Bu(t) ) ligand bridges in an asymmetric manner via a sulfur and nitrogen donor, paddlewheel compounds of the type M(2)[mim (Bu(t) )](4) may exist as isomers that are distinguished by the relative orientations of the ligands. In this  ...[more]

Similar Datasets

| S-EPMC9846696 | biostudies-literature
| S-EPMC6690448 | biostudies-literature
| S-EPMC5659211 | biostudies-literature
| S-EPMC2987641 | biostudies-literature
| S-EPMC10863395 | biostudies-literature
| S-EPMC9933481 | biostudies-literature
| S-EPMC8147896 | biostudies-literature
| S-EPMC8303679 | biostudies-literature
| S-EPMC7513363 | biostudies-literature
| S-EPMC6017743 | biostudies-literature