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Dependence of macroscopic wetting on nanoscopic surface textures.


ABSTRACT: The hydrophobicity of a surface can be enhanced by physical textures. However, no existing theories of surface wetting can provide guidance to pinpoint the texture size requirement to achieve super/ultrahydrophobicity. Here, we show that the three-phase contact line tension, tau, is an important link to understand the dependence of macroscopic wetting on physical texture size in an ideal Cassie regime. Specifically, we show that texture size is the dominant parameter in determining surface hydrophobicity when the size approaches a limiting physical length scale, as defined by tau and the surface tension of the liquid.

SUBMITTER: Wong TS 

PROVIDER: S-EPMC2783847 | biostudies-literature | 2009 Nov

REPOSITORIES: biostudies-literature

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Dependence of macroscopic wetting on nanoscopic surface textures.

Wong Tak-Sing TS   Ho Chih-Ming CM  

Langmuir : the ACS journal of surfaces and colloids 20091101 22


The hydrophobicity of a surface can be enhanced by physical textures. However, no existing theories of surface wetting can provide guidance to pinpoint the texture size requirement to achieve super/ultrahydrophobicity. Here, we show that the three-phase contact line tension, tau, is an important link to understand the dependence of macroscopic wetting on physical texture size in an ideal Cassie regime. Specifically, we show that texture size is the dominant parameter in determining surface hydro  ...[more]

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