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ABSTRACT:
SUBMITTER: Chiang KP
PROVIDER: S-EPMC2791996 | biostudies-literature | 2009 Jun
REPOSITORIES: biostudies-literature
Chiang Karen P KP Barrett Pamela M PM Ding Feizhi F Smith Jeremy M JM Kingsley Savariraj S Brennessel William W WW Clark Meghan M MM Lachicotte Rene J RJ Holland Patrick L PL
Inorganic chemistry 20090601 12
A series of three- and four-coordinate iron(II) complexes with nitrogen, chlorine, oxygen, and sulfur ligands is presented. The electronic variation is explored by measuring the association constant of the neutral ligands and the reduction potential of the iron(II) complexes. Varying the neutral ligand gives large changes in K(eq), which decrease in the order CN(t)Bu > pyridine >2-picoline > DMF > MeCN > THF > PPh(3). These differences can be attributed to a mixture of steric effects and electro ...[more]