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Valence tautomerism in titanium enolates: catalytic radical haloalkylation and application in the total synthesis of neodysidenin.


ABSTRACT: A direct ruthenium-catalyzed radical chloroalkylation of N-acyl oxazolidinones capitalizing on valence tautomerism of titanium enolates has been developed. The chloroalkylation method served as the centerpiece in the enantioselective total synthesis of trichloroleucine-derived marine natural product neodysidenin.

SUBMITTER: Beaumont S 

PROVIDER: S-EPMC2819066 | biostudies-literature |

REPOSITORIES: biostudies-literature

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