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Unusual bridging of three nitrates with two bridgehead protons in an octaprotonated azacryptand.

ABSTRACT: Structural analysis of the nitrate complex of a thiophene-based azacryptand suggests that three nitrates are bridged with two bridgehead protons which play the topological role of two transition metal ions in a classical Werner type coordination complex bridging three anions.

SUBMITTER: Saeed MA 

PROVIDER: S-EPMC2834291 | biostudies-literature | 2010 Jan

REPOSITORIES: biostudies-literature

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Unusual bridging of three nitrates with two bridgehead protons in an octaprotonated azacryptand.

Saeed Musabbir A MA   Fronczek Frank R FR   Huang Ming-Ju MJ   Alamgir Hossain Md M  

Chemical communications (Cambridge, England) 20091203 3

Structural analysis of the nitrate complex of a thiophene-based azacryptand suggests that three nitrates are bridged with two bridgehead protons which play the topological role of two transition metal ions in a classical Werner type coordination complex bridging three anions. ...[more]

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