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An Enantioselective Synthesis of the ABD Tricycle for (-)-Phomactin A Featuring Rawal's Asymmetric Diels-Alder Cycloaddition.

ABSTRACT: An enantioselective synthesis of the ABD-ring of (-)-phomactin A is described here. The sequence features Rawal's asymmetric Diels-Alder cycloaddition. The overall length is significantly reduced from our previous attempt.

SUBMITTER: You LF 

PROVIDER: S-EPMC2846367 | biostudies-literature | 2008 Dec

REPOSITORIES: biostudies-literature

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An Enantioselective Synthesis of the ABD Tricycle for (-)-Phomactin A Featuring Rawal's Asymmetric Diels-Alder Cycloaddition.

You Ling-Feng LF   Hsung Richard P RP   Bedermann Aaron A AA   Kurdyumov Aleksey V AV   Tang Yu Y   Buchanan Grant S GS   Cole Kevin P KP  

Advanced synthesis & catalysis 20081201 18

An enantioselective synthesis of the ABD-ring of (-)-phomactin A is described here. The sequence features Rawal's asymmetric Diels-Alder cycloaddition. The overall length is significantly reduced from our previous attempt. ...[more]

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