Intermediates in reactions of copper(I) complexes with N-oxides: from the formation of stable adducts to oxo transfer.
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ABSTRACT:
SUBMITTER: Hong S
PROVIDER: S-EPMC2878392 | biostudies-literature | 2009 Jul
REPOSITORIES: biostudies-literature
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Intermediates in reactions of copper(I) complexes with N-oxides: from the formation of stable adducts to oxo transfer.
Hong Sungjun S Gupta Aalo K AK Tolman William B WB
Inorganic chemistry 20090701 14
Reactions of copper(I) complexes of bidentate N-donor supporting ligands with pyridine- and trimethylamine-N-oxides or PhIO were explored. Key results include the identification of novel copper(I) N-oxide adducts, aryl substituent hydroxylation, and bis(mu-oxo)dicopper complex formation via a route involving oxo transfer. ...[more]
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