Homogeneity of phytochrome Cph1 vibronic absorption revealed by resonance Raman intensity analysis.
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ABSTRACT:
SUBMITTER: Spillane KM
PROVIDER: S-EPMC2880177 | biostudies-literature | 2009 Oct
REPOSITORIES: biostudies-literature
Publications
Homogeneity of phytochrome Cph1 vibronic absorption revealed by resonance Raman intensity analysis.
Spillane Katelyn M KM Dasgupta Jyotishman J Lagarias J Clark JC Mathies Richard A RA
Journal of the American Chemical Society 20091001 39
Phytochromes are an important class of red/far-red responsive photoreceptors that act as light-activated biological switches, ultimately driving growth and development in plants, bacteria, and fungi. The composition of the red-absorbing ground-state has been widely debated due to the presence of a shoulder feature on the blue edge of electronic absorption spectra, which many have attributed to the presence of multiple ground-state conformers. Here we use resonance Raman intensity analysis to cal ...[more]
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