Mononuclear copper complex-catalyzed four-electron reduction of oxygen.
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ABSTRACT:
SUBMITTER: Fukuzumi S
PROVIDER: S-EPMC2886287 | biostudies-literature | 2010 May
REPOSITORIES: biostudies-literature
Publications
Mononuclear copper complex-catalyzed four-electron reduction of oxygen.
Fukuzumi Shunichi S Kotani Hiroaki H Lucas Heather R HR Doi Kaoru K Suenobu Tomoyoshi T Peterson Ryan L RL Karlin Kenneth D KD
Journal of the American Chemical Society 20100501 20
A mononuclear Cu(II) complex acts as an efficient catalyst for four-electron reduction of O(2) to H(2)O. Its reduction by a ferrocene derivative (Fc*) and reaction with O(2) leads to the formation of a peroxodicopper(II) complex; this is subsequently reduced by Fc* in the presence of protons to regenerate the Cu(II) complex. ...[more]
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