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Systematic Synthesis of a Metal Organic Framework Based on Triangular Cu(3)(?(3)-OH) Secondary Building Units: From a 0-D Complex, to an 1-D Chain and a 3-D Lattice

ABSTRACT: Reactions of Cu(CF(3)SO(3))(2) and pyrazole in methanolic solutions in the presence of stoichiometric amounts of py, py/4,4'-bpy, or 4,4'-bpy have yielded two new complexes [Cu(3)(?(3)-OH)(?-pz)(3)(py)(3)](CF(3)SO(3))(2)·0.5H(2)O (1) and [{Cu(3)(?(3)-OH)(?-pz)(3)(py)(2)}(2)(?-4,4'-bpy)](CF(3)SO(3))(4) (2), a one-dimensional coordination polymer, {[Cu(3)(?(3)-OH)(?-pz)(3)(py)(?-4,4'-bpy)](CF(3)SO(3))(2)·0.5H(2)O}(n) (3), and a three-dimensional, eight-fold interpenetrated extended lattice, {[Cu(3)(?(3)-OH)(?-pz)(3)(?-4,4'-bpy)(1.5)](CF(3)SO(3))(2)·1.5H(2)O}(n) (4).

SUBMITTER: Rivera-Carrillo M 

PROVIDER: S-EPMC2898198 | biostudies-literature | 2010 Jan

REPOSITORIES: biostudies-literature

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"Systematic Synthesis of a Metal Organic Framework Based on Triangular Cu(3)(μ(3)-OH) Secondary Building Units: From a 0-D Complex, to an 1-D Chain and a 3-D Lattice"

Rivera-Carrillo Marlyn M   Chakraborty Indranil I   Raptis Raphael G RG  

Crystal growth & design 20100101 6

Reactions of Cu(CF(3)SO(3))(2) and pyrazole in methanolic solutions in the presence of stoichiometric amounts of py, py/4,4'-bpy, or 4,4'-bpy have yielded two new complexes [Cu(3)(μ(3)-OH)(μ-pz)(3)(py)(3)](CF(3)SO(3))(2)·0.5H(2)O (1) and [{Cu(3)(μ(3)-OH)(μ-pz)(3)(py)(2)}(2)(μ-4,4'-bpy)](CF(3)SO(3))(4) (2), a one-dimensional coordination polymer, {[Cu(3)(μ(3)-OH)(μ-pz)(3)(py)(μ-4,4'-bpy)](CF(3)SO(3))(2)·0.5H(2)O}(n) (3), and a three-dimensional, eight-fold interpenetrated extended lattice, {[Cu(3  ...[more]

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